Electrolyte Solvation Engineering Stabilizing Anode‐Free Sodium Metal Battery With 4.0 V‐Class Layered Oxide Cathode
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Y Zou, B Zhang, H Luo, X Yu, M Yang…
Advanced …, 2024
Wiley Online Library
Anode‐free sodium metal batteries (AFSMBs) are regarded as the “ceiling” for current sodium‐based batteries. However, their practical application is hindered by the unstable electrolyte and interfacial chemistry at the high‐voltage cathode and anode‐free side, especially under extreme temperature conditions. Here, an advanced electrolyte design strategy based on electrolyte solvation engineering is presented, which shapes a weakly solvating anion‐stabilized (WSAS) electrolyte by balancing the interaction between the Na …
