Direct alkylation of glycine derivatives via photoinduced palladium catalysis, utilizing intermolecular hydrogen atom transfer mediated by alkyl radicals
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S Yang, H Hu, J Li, M Chen
ACS Catalysis, 2023
ACS Publications
Unveiling the alkyl/Pd hybrid species is a unique sp3-C-centered radical for facilitating intermolecular hydrogen atom transfer (HAT) in the development of direct alkylation of glycine derivatives. This transformative reaction proceeds smoothly under simple and mild conditions, exhibiting impressive versatility in terms of substrate scope encompassing both glycine derivatives and alkyl bromides while showcasing remarkable tolerance toward diverse functional groups. To shed light on the underlying mechanism, extensive …
