Glycosyl Thiosulfonate-Enabled Ortho-Thiolation via the Catellani Strategy: A Modular Synthesis of Polysubstituted Aryl Thioglycosides
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Z Azeem, N Malya, R Kant, SK Mudedla…
Organic Chemistry …, 2026
pubs.rsc.org
Site-selective introduction of a glycosylthiol group into aromatic compounds is a crucial process in organic chemistry. However, the position that a glycosylthiol moiety can be introduced to is largely restricted to a pre-functionalized site; otherwise, electronically biased substrates or auxiliary groups are needed. Moreover, common ways to prepare stereoselective aryl thioglycosides often rely on cross-coupling reactions between aryl halides and glycosylthiols. These methods form carbon-sulfur (CS) bonds at the ipso …
