碱金属氧化物和碱土金属氧化物对活性炭负载钌催化剂合成氨的促进剂作用。
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K Aika, T Kawahara, S Murata, T Onishi
Bulletin of the Chemical …, 1990
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Promoter effects of alkali metal nitrates and alkali earth metal nitrates on Ru/AC (active carbon) were studied in order to prepare an effective catalyst for ammonia synthesis. Of alkali metal nitrates, RbNO 3 was more effective than C s NO 3 and KNO 3. Alkali earth metal (Mg, Ca, Sr, Ba) nitrates were also found to be effective promoters on Ru/AC catalysts. Of them heavier alkali earth metal elements were more effective (Ba> Sr> Ca> Mg). Ba (NO 3) 2 was as effective as CSNO 3, which was not expected from the stand point of …