Norbornene and Base-Regulated Divergent Synthesis of Fluorenones and Phenanthrenes from Aryl Halides and 2-Halomandelic Acids
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Y Fu, Y Luo, W Yang, L Jia, J Xiu, L Ma, Z Du
Organic Letters, 2026
ACS Publications
A palladium-catalyzed, norbornene- and norbornadiene-mediated Catellani-type annulation reaction of haloarenes with 2-halomandelic acids prepared 9-fluorenones and phenanthrenes, respectively. Theoretical investigations suggest that, within the norbornene-engaged cascades, more reactive 2-(2-bromophenyl)-2-oxoacetic acid was generated and participated in ensuing transformations. In contrast, for processes mediated by norbornadiene, 2-bromomandelic acid was converted into its dipotassium salt to participate in the following cascade.ACS Publications展开收起保存 引用 相关文章 所有 3 个版本
