Synthesis of 10-phenanthrenol derivatives via visible light catalyzed itramolecular cycloaromatization
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Q Teng, L Xu, D Cheng, X Xu
Chin. J. Org. Chem, 2020
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Phenanthrene derivatives play an important role in pharmaceutical chemistry and material science. Due to its advantages of green, mild reaction conditions and great application potential, visible light catalysis has become a powerful tool in organic synthesis. In this paper, under the catalysis of photocatalyst Ir [dF (CF 3) ppy] 2 (dtbbpy) PF 6, a series of 10-phenanthrenol derivatives were synthesized from 2-arylbenzoyl acetate derivatives in moderate to good yields through intramolecular cycloaromatization. In addition, the …
