Structure-reactivity relationships in reactions of alkane radical cations: Study of the proton transfer from alkane radical cations to alkane molecules in γ-irradiated …
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J Ceulemans
Spectrochimica Acta Part A: Molecular and …, 1998
Elsevier
A summary is presented of ESR results obtained in γ-irradiated disordered CCl3F/alkane systems at cryogenic temperatures, with respect to proton-donor site selectivity in the proton transfer from alkane radical cations to alkane molecules. The nature of the alkyl radicals formed by proton transfer is indicative for the site of proton donation and is derived unambiguously from ESR results by comparison with powder spectra of authentic isomeric alkyl radicals, obtained by γ-irradiation of various chloro and bromoalkanes in perdeuterated …
