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Enantioselective C(sp3)–C(sp3) bond formation by synergistic thiamine-dependent radical biocatalysis and photoredox catalysis复制

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J Chun, Y Bao, Q Zhang, X Hou, Z Wu, H Sun, Z Xing…
Nature Catalysis, 2026
nature.com
… alkyl radicals remains a substantial challenge. Here we synergistically repurpose a
thiamine-dependent benzoylformate decarboxylase (PpBFD) with a photoinduced radical process, …

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