Mercury-catalyzed rearrangement of ketoximes into amides and lactams in acetonitrile
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C Ramalingan, YT Park
The Journal of organic chemistry, 2007
ACS Publications
… Hence, more efficient and milder catalytic methods for the transformation of ketoximes
into amides/lactams as well as diversification of the rearrangement are highly desirable. We
recently reported the Beckmann rearrangement of a diverse range of ketoximes into their
corresponding amides/lactams by mesitylenesulfonyl chloride in one pot. In continuation of
the research directed toward an efficient and mild methodology for the Beckmann
rearrangement, we described herein a mercury-catalyzed Beckmann rearrangement of …
