Visible-light-facilitated P-center radical addition to C [double bond, length as m-dash] X (X= C, N) bonds results in cyclizations
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C Li, J Wang, SD Yang
Chemical Communications, 2021
pubs.rsc.org
Visible-light-facilitated phosphorus radical reactions have been developed as a powerful and sustainable tool for the synthesis of various organophosphorus compounds. In general, these reactions require stoichiometric amounts of oxidants, and reductants, bases, and radical initiators, leading to uneconomical and complicated processes. Progress has been made over the past few years toward using reactions that proceed under eco-benign and mild reaction conditions. Furthermore, these reactions have broad functional group …
