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Native Carboxylate Assisted Palladium/Norbornene Mediated Distal CH functionalization of Ferrocene复制

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P Gupta, B Patel, S Waske, S Madhavan…
Chemical …, 2026
pubs.rsc.org
Herein, we disclose a ligand-enabled, auxiliary-free, native carboxylate assisted Pd/norbornene (NBE) mediated highly regioselective C (3)-arylation of commercially available ferrocene carboxylic acids. This unique approach utilizes the Catellani-type reaction for the distal CH activation in ferrocene where the weak chelation-assisted palladacycle formed by proximal CH activation relays the palladium to the distal C (3)-position mediated by NBE, resulting into CC bond formation with aryl iodides.

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