Native Carboxylate Assisted Palladium/Norbornene Mediated Distal CH functionalization of Ferrocene
1. 请及时下载文件确认是否正确, 系统将在 2026-04-03 16:50:28 删除文件
2. 如若文件有误请驳回应助文件, 求助状态即回到求助中
3. 如若文件正确请及时点击确认, 若超过时后系统自动默认为已完结
注: 所有应助的资源仅供学习交流使用, 不得违反相关法律法规
DOI:
文献链接:
其他信息:
P Gupta, B Patel, S Waske, S Madhavan…
Chemical …, 2026
pubs.rsc.org
Herein, we disclose a ligand-enabled, auxiliary-free, native carboxylate assisted Pd/norbornene (NBE) mediated highly regioselective C (3)-arylation of commercially available ferrocene carboxylic acids. This unique approach utilizes the Catellani-type reaction for the distal CH activation in ferrocene where the weak chelation-assisted palladacycle formed by proximal CH activation relays the palladium to the distal C (3)-position mediated by NBE, resulting into CC bond formation with aryl iodides.
