Cobalt-Catalyzed Alkene Hydrohalogenation via Hydrogen Atom Transfer
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A Khosravi, MY Ngai
Tetrahedron, 2025
Elsevier
Alkene hydrohalogenation is a fundamental transformation for the synthesis of organohalides, key intermediates in organic synthesis, pharmaceuticals, and materials science. Traditional ionic methods with hydrogen halides are limited by harsh conditions, poor functional group tolerance, and regioselectivity issues. Recently, cobalt-catalyzed hydrohalogenation via metal-hydride hydrogen atom transfer (MHAT) has emerged as a versatile and radical-based alternative, enabling mild conditions, broad functional group …
