Nickel and cobalt-catalyzed coupling of alkyl halides with alkenes via Heck reactions and radical conjugate addition
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Q Qian, Z Zang, Y Chen, W Tong…
Mini Reviews in …, 2013
ingentaconnect.com
Cross-coupling of alkyl halides with alkenes leading to Heck-type and addition products is summarized. The development of Heck reaction with aliphatic halides although has made significant progress in the past decade and particularly recently, it was much less explored in comparison with the aryl halides. The use of Ni-and Co-catalyzed protocols allowed efficient Heck coupling of activated and unactivated alkenes with 1º, 2º and 3º alkyl halides. In addition, radical conjugate addition to activated alkenes has become a well-established …
