Palladium/norbornene cooperative catalysis triple functionalization: carbamoylation/double-annulation of (hetero) aryl iodides
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YX Chai, YF Yang, FY Zhang, JY Zhao…
Chemical …, 2025
pubs.rsc.org
A novel Pd/NBE-catalyzed intermolecular dehydrobicyclization of heteroaryl iodides for the synthesis of polycyclic nitrogen-containing heterocycles is reported. In this work, the N-protected aryl carbamoyl chloride serves as a source of acylation. The products resulting from the direct C–H functionalization of heteroaryl iodides are smoothly obtained without catalyst poisoning by heteroatoms.
