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Transition-metal–free borylative functionalization of aryl fluorides with boron alkoxide in the presence of sodium dispersion复制

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S Ikeda, U Ogi, K Okano, A Mori
Chemical Communications, 2025
pubs.rsc.org
Borylative functionlization of an aryl fluoride was performed using a transition-metal–free process with sodium dispersion (SD). The reaction of 4-fluorobiphenyl with boron alkoxide (iPrOBpin) in the presence of SD afforded the borylated product in up to 62% yield. The borylation reaction proceeded with several aryl fluorides in good to excellent yields.

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