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Intramolecular Heck reactions of unactivated alkyl halides复制

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L Firmansjah, GC Fu
Journal of the American Chemical Society, 2007
ACS Publications
A method has been developed for achieving palladium-catalyzed intramolecular Heck reactions of unactivated, β-hydrogen-containing alkyl bromides and chlorides. The data from a stereochemical investigation are consistent with carbon− carbon bond formation via an alkylpalladium, rather than a radical, intermediate.

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