Oxetanes as Alkylating Reagents for Palladium/Norbornene Cooperative Catalysis
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J Tan, C Jiao, R Chen, X Li, Q Zhou, HG Cheng
Synthesis, 2026
thieme-connect.com
We report the use of oxetanes as the alkylating reagents for palladium/norbornene cooperative catalysis, significantly expanding the scope of this powerful transformation. The key to this advancement relies on the activation of oxetanes using HCl or AlCl 3. Salient features of this process include readily available starting materials regarding aryl iodides, oxetanes, and ipso-terminating reagents, exceptional functional group tolerance, and good step-economy. In addition, this approach provides direct and efficient access to …
