Cationic Allylic Pd Complexes With Phosphine‐Thioether Ligands for Vinyl‐Addition Polymerization of Norbornene
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GO Karpov, AD Knyazeva, AA Danshina…
Applied …, 2026
Wiley Online Library
ABSTRACT A series of new cationic Pd‐allyl complexes were synthesized using bidentate phosphine‐thioether (P~ S) ligands. The structures of the corresponding (P~ S) Pd (allyl) complexes were thoroughly characterized by NMR spectroscopy, high‐resolution mass spectrometry, and X‐ray crystallography. These synthesized complexes were employed as single‐component catalysts for the vinyl‐addition polymerization of norbornene and its derivatives. The catalysts exhibited moderate activity (up to 4.48 g· mmol− 1· h− 1) upon …
