Visible-light-induced acylation of active olefins by a C–C bond cleavage/Smiles rearrangement radical relay strategy via EDA complexes
1. 文件大小不能超过300M, 允许上传文档或压缩包等
2. 请确保上传文献的真实性、完整性，不得对原文做任何修改
注: 所有应助的资源仅供学习交流使用, 不得违反相关法律法规
DOI:
文献链接:
其他信息:
LJ Zhong, SD Li, XH Ma, PF Huang, Q Zhou…
Organic Chemistry …, 2026
pubs.rsc.org
Photoinduced C–C bond activation of acyl oxime esters to generate aliphatic and aryl acyl radicals typically requires noble metal photocatalysts or synthetically elaborate organic dyes. In contrast, electron donor–acceptor (EDA) complex photochemistry has emerged as a powerful strategy in organic synthesis, offering operational simplicity and the potential to generate radicals via single electron transfer under visible-light irradiation without any photocatalysts. Herein, we report the first visible-light-induced EDA-complex-promoted …
