Visible-light-induced acylation of active olefins by a C–C bond cleavage/Smiles rearrangement radical relay strategy via EDA complexes
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LJ Zhong, SD Li, XH Ma, PF Huang, Q Zhou…
Organic Chemistry …, 2026
pubs.rsc.org
Photoinduced C–C bond activation of acyl oxime esters to generate aliphatic and aryl acyl radicals typically requires noble metal photocatalysts or synthetically elaborate organic dyes. In contrast, electron donor–acceptor (EDA) complex photochemistry has emerged as a powerful strategy in organic synthesis, offering operational simplicity and the potential to generate radicals via single electron transfer under visible-light irradiation without any photocatalysts. Herein, we report the first visible-light-induced EDA-complex-promoted …
