Palladium-catalyzed reductive conversion of acyl fluorides via ligand-controlled decarbonylation
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Y Ogiwara, Y Sakurai, H Hattori, N Sakai
Organic letters, 2018
ACS Publications
Ligand-controlled non-decarbonylative and decarbonylative conversions of acyl fluorides were developed using a Pd (OAc) 2/Et3SiH combination. When tricyclohexylphosphine (PCy3) was used as the ligand, aldehydes were obtained as simple reductive conversion products. The use of 1, 2-bis (dicyclohexylphosphino) ethane (Cy2P (CH2) 2PCy2, DCPE) as the ligand, however, favored the formation of hydrocarbons, which are decarbonylative reduction products.
